In 2007, di María was picked to play for the Argentina Under-20 squad. He was capped for the 2007 South American Youth Championship in Paraguay. In 2007, he was called up for the FIFA U-20 World Cup in Canada. They went on to win the tournament with di María scoring three goals in the process.
On 28 January 2008, di María and some of his U-20 teammates were called up for the Argentina squad for the 2008 Beijing Olympics. He scored the extra-time game-winning goal on a pass from Lionel Messi in the 105th minute of his team's 2–1 quarterfinal win over the Netherlands.
On 23 August, di María scored the game-winner, a chip over the keeper from the edge of the area in the 57th minute of Argentina's 1–0 victory against Nigeria to capture their second straight Olympic Gold Medal in the final game of the Olympic tournament.[21]
Di María was chosen as one of the 23 players for the 2010 FIFA World Cup. On 11 August 2010, he scored the first ever international goal at Dublin's new Aviva Stadium in a friendly against Ireland with Argentina winning 1–0.[22]
Personal life
Di María married his girlfriend of two years, Jorgelina Cardoso, in Argentina at the end of July 2011. Jorgelina is from Rosario, Argentina. Giannina Maradona and her child were also in attendance.His father was also a footballer, who played for River Plate's reserves.